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(1S)-(-)-Camphanic chloride_Molecular_structure_CAS_39637-74-6)
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(1S)-(-)-Camphanic chloride

Catalog No. 21287 Name Sigma Aldrich
CAS Number 39637-74-6 Website http://www.sigmaaldrich.com
M. F. C10H13ClO3 Telephone 1-800-521-8956
M. W. 216.66142 Fax
Purity ≥98.0% (AT) Email
Storage Chembase ID: 137486

SYNONYMS

Title
(1S)-(-)-莰烷酰氯
IUPAC name
(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
IUPAC Traditional name
(1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
Synonyms
(-)-莰烷酰氯
(1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
(1S)-3-氧代-4,7,7-三甲基-2-氧杂双环[2.2.1]庚烷-1-甲酰氯
(-)-Camphanoyl chloride

DATABASE IDS

CAS Number 39637-74-6
MDL Number MFCD00135626
PubChem SID 24852750
EC Number 254-552-4
Beilstein Number 3590860

PROPERTIES

European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Storage Temperature -20°C
Hazard Class 8
UN Number 3261
Packing Group 2
German water hazard class 3
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
Grade for chiral derivatization
Linear Formula C10H13O3Cl
Optical Purity enantiomeric ratio: ≥99.5:0.5 (GC)
Purity ≥98.0% (AT)
Purity ≥98.0%
Melting Point 67-70 °C
Melting Point 71-73 °C(lit.)
Optical Rotation [α]20/D -18±1°, c = 2% in carbon tetrachloride

DETAILS

Description (English)
Other Notes
Chiral derivatizing reagent used for the determination of enantiomeric purity of alcohols and amines by HPLC 1,2,3,4
Description (简体中文)
Other Notes
作为 HPLC 检测醇和胺对映体纯度的手性衍生化试剂1,2,3,4

REFERENCES