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(R)-(-)-α-Methoxyphenylacetic acid_Molecular_structure_CAS_3966-32-3)
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(R)-(-)-α-Methoxyphenylacetic acid

Catalog No. 65209 Name Sigma Aldrich
CAS Number 3966-32-3 Website http://www.sigmaaldrich.com
M. F. C9H10O3 Telephone 1-800-521-8956
M. W. 166.1739 Fax
Purity ≥99.0% (T) Email
Storage Chembase ID: 130932

SYNONYMS

Title
(R)-(-)-α-甲氧基苯乙酸
IUPAC name
(2R)-2-methoxy-2-phenylacetic acid
IUPAC Traditional name
(R)-methoxy(phenyl)acetic acid
Synonyms
O-Methyl-D-mandelic acid
O-甲基-D-扁桃酸

DATABASE IDS

Beilstein Number 2209198
MDL Number MFCD00004250
CAS Number 3966-32-3
PubChem SID 24883692
EC Number 223-580-9

PROPERTIES

Grade for chiral derivatization
Linear Formula C6H5CH(OCH3)CO2H
Optical Purity enantiomeric ratio: ≥99.5:0.5 (HPLC)
Purity ≥99.0% (T)
Purity ≥99.0%
Melting Point 64-67 °C
Melting Point 66-68 °C(lit.)
Optical Rotation [α]20/D -149±2°, c = 0.5% in ethanol
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Other Notes
Chiral reagent for the det. of enantiomeric purity and absolute configuration of sec-alcohols and α-chiral amines by NMR1,2; Analysis of amines using the ONSu ester3,4
Description (简体中文)
Other Notes
用于通过 NMR 测定仲醇和 α-手性胺对映体纯度和绝对构型的手性试剂1,2;使用 ONSu 酯分析胺3,4

REFERENCES