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Bromotris(dimethylamino)phosphonium hexafluorophosphate_Molecular_structure_CAS_50296-37-2)
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Bromotris(dimethylamino)phosphonium hexafluorophosphate

Catalog No. 18570 Name Sigma Aldrich
CAS Number 50296-37-2 Website http://www.sigmaaldrich.com
M. F. C6H18BrF6N3P2 Telephone 1-800-521-8956
M. W. 388.0691612 Fax
Purity ≥98.0% (AT) Email
Storage Chembase ID: 150771

SYNONYMS

Title
溴代三(二甲基氨基)磷鎓六氟磷酸盐
IUPAC name
bromotris(dimethylamino)phosphanium; hexafluoro-λ5-phosphanuide
IUPAC Traditional name
bromotris(dimethylamino)phosphanium hexafluorophosphate
Synonyms
BroP
Bromotris(N-methylmethanaminato)-phosphorus hexafluorophosphate

DATABASE IDS

MDL Number MFCD00191864
PubChem SID 24851158
CAS Number 50296-37-2

PROPERTIES

Grade purum
Linear Formula BrP[N(CH3)2]3PF6
Purity ≥98.0% (AT)
Melting Point >300 °C(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H314-H350
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P201-P280-P305 + P351 + P338-P310
RID/ADR UN 3263 8/PG 2
Risk Statements 45-34
Safety Statements 53-26-36/37/39-45
Hazard Class 8
UN Number 3263
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
General description
may contain ≥0.1% HMPT
Other Notes
Coupling reagent for N-methyl amino acids without racemization7; Coupling of α,α-dialkyl amino acids, e.g. AIB8
Application
Reagent for: Conjugate addition of nitroalkanes to an acrylate equivalent1 A novel polymer supported approach to nucleoside modification2 Asymmetric hydrogenations3 Peptide coupling4 Pyrrolidine hydroxylation5 Synthesis of cyclic PNA-based compound directed against HIV-1 TAR RNA6
Description (简体中文)
General description
可能含 ≥0.1% 的 HMPT
Other Notes
无外消旋作用的 N-甲基氨基酸偶联试剂7;可用于 α,α-二烷基氨基酸,如 AIB 的偶联反应8
Application
Reagent for: Conjugate addition of nitroalkanes to an acrylate equivalent1 A novel polymer supported approach to nucleoside modification2 Asymmetric hydrogenations3 Peptide coupling4 Pyrrolidine hydroxylation5 Synthesis of cyclic PNA-based compound directed against HIV-1 TAR RNA6

REFERENCES