2-(Chloromethyl)allyl-trimethylsilane

• Catalog No.: 25037
• CAS Number: 18388-03-9
• M. F.: C7H15ClSi
• M. W.: 162.7325
• Purity: ≥97.0% (GC)

SYNONYMS

• Title: 2-(氯甲基)烯丙基-三甲基硅烷
• IUPAC name: [2-(chloromethyl)prop-2-en-1-yl]trimethylsilane
• IUPAC Traditional name: [2-(chloromethyl)prop-2-en-1-yl]trimethylsilane
• Synonyms: 2-(氯甲基)-3-三甲基硅基-1-丙烯; 2-(Trimethylsilylmethyl)allyl chloride; 2-(三甲基甲硅烷基甲基)烯丙基氯; 2-(Chloromethyl)-3-trimethylsilyl-1-propene

DATABASE IDS

• Beilstein Number: 1747038
• MDL Number: MFCD00013253
• CAS Number: 18388-03-9

PROPERTIES

• Grade: purum
• Linear Formula: (CH3)3SiCH2C(CH2Cl)=CH2
• Purity: ≥97.0% (GC)
• Boiling Point: 162-163 °C/768 mmHg(lit.)
• Density: 0.899 g/mL at 25 °C(lit.)
• Flash Point: 43 °C
• Flash Point: 109.4 °F
• Refractive Index: n20/D 1.453(lit.)
• Refractive Index: n20/D 1.453
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• RID/ADR: UN 1993 3/PG 3
• Risk Statements: 10-36/37/38
• Safety Statements: 26-36
• Hazard Class: 3
• UN Number: 1993
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Three-carbon annulating reagent reacting via [3+2] CA1,2; Annulation via alkylation3

Description (简体中文)

Other Notes
通过 [3+2] 环加成机理1,2发生反应的三碳环化剂；通过烷化反应3成环