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(R)-(+)-N,α-Dimethylbenzylamine_Molecular_structure_CAS_5933-40-4)
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(R)-(+)-N,α-Dimethylbenzylamine

Catalog No. 68620 Name Sigma Aldrich
CAS Number 5933-40-4 Website http://www.sigmaaldrich.com
M. F. C9H13N Telephone 1-800-521-8956
M. W. 135.20622 Fax
Purity ≥96.0% (sum of enantiomers, GC) Email
Storage Chembase ID: 148888

SYNONYMS

Title
R-N-甲基-苯乙胺
IUPAC name
methyl[(1R)-1-phenylethyl]amine
IUPAC Traditional name
methyl[(1R)-1-phenylethyl]amine
Synonyms
(R)-(+)-N-甲基-1-苯乙胺
(R)-(+)-N-Methyl-1-phenylethylamine

DATABASE IDS

PubChem SID 24885695
CAS Number 5933-40-4
Beilstein Number 4350160
MDL Number MFCD00044966

PROPERTIES

Grade purum
Linear Formula C6H5CH(CH3)NHCH3
Purity ≥96.0% (sum of enantiomers, GC)
Boiling Point 74-76 °C/11 mmHg(lit.)
Density 0.924 g/mL at 20 °C(lit.)
Flash Point 61 °C
Flash Point 141.8 °F
Optical Rotation [α]20/D +74±4°, c = 2% in chloroform
Refractive Index n20/D 1.511(lit.)
Refractive Index n20/D 1.511
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H302-H312-H314-H332
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2619 8/PG 2
Risk Statements 20/21/22-34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2619
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Chiral secondary amine used as auxiliary, e.g. detn. of absolute configuration of carboxylic acids1; Asymmetric addition of cuprates to enones2; Preparation of chiral thiophosphonate3
Description (简体中文)
Other Notes
手性仲胺可作为辅助剂,用于如羧酸绝对构型的测定1;铜酸盐的不对称加成反应生成烯酮2;手性硫代膦酸盐的制备3

REFERENCES