Triphenylphosphine-copper(I) hydride Hexamer

• Catalog No.: 93099
• CAS Number: 33636-93-0
• M. F.: C108H90Cu6P6
• M. W.: 1954.988766

SYNONYMS

• Title: 三苯基膦-氢化铜六聚体(I)
• IUPAC name: hexakis(triphenylphosphane) hexakis(λ^1-copper)
• IUPAC Traditional name: hexakis(triphenylphosphine) hexakis(λ^1-copper)
• Synonyms: Stryker’s reagent; Cuprous hydride triphenylphosphine hexamer; Stryker 试剂; 三苯基磷酸亚酮六聚体

DATABASE IDS

• CAS Number: 33636-93-0
• MDL Number: MFCD00221518
• PubChem SID: 24889794

PROPERTIES

• Grade: purum
• Linear Formula: [(C6H5)3PCuH]6
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Reducing agent for the selective reduction of α,β-unsaturated carbonyls to the carbonyls8,9,10,11; Catalyst for reductions with hydrogen12
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7

Description (简体中文)

Other Notes
还原剂，用于生成羰基化合物的 α,β-不饱和羰基化合物的选择还原反应8,9,10,11；催化剂，用于氢的还原反应12
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7