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o-Phenylene phosphorochloridate_Molecular_structure_CAS_1499-17-8)
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o-Phenylene phosphorochloridate

Catalog No. 78400 Name Sigma Aldrich
CAS Number 1499-17-8 Website http://www.sigmaaldrich.com
M. F. C6H4ClO3P Telephone 1-800-521-8956
M. W. 190.520921 Fax
Purity ≥90% (AT) Email
Storage Chembase ID: 149152

SYNONYMS

Title
邻亚苯基氯膦酸
IUPAC name
2-chloro-2H-1,3,2λ5-benzodioxaphosphol-2-one
IUPAC Traditional name
2-chloro-1,3,2λ5-benzodioxaphosphol-2-one
Synonyms
2-氯-1,3,2-二氧环磷烯2-氧化物
Catechol cyclophosphorochloridate
2-Chloro-1,3,2-benzodioxaphosphole 2-oxide
o-Phenylene chlorophosphate
氯磷酸-1,2-亚苯基二酯

DATABASE IDS

CAS Number 1499-17-8
EC Number 216-106-7
Beilstein Number 142368
MDL Number MFCD00005854

PROPERTIES

Empirical Formula (Hill Notation) C6H4ClO3P
Grade technical
Purity ≥90% (AT)
Boiling Point 120 °C/9 mmHg(lit.)
Melting Point 56-62 °C
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 2
Risk Statements 14-34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 3261
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Phosphorylating agent which reacts rapidly with alcohols4,5,6
Application
Reactant for preparation of:
• Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity1
• Vinyloxy phosphorus monomers2
• Phosphorylation agent3
Description (简体中文)
Other Notes
可以快速地与醇反应的磷酸化试剂4,5,6
Application
Reactant for preparation of:
• Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity1
• Vinyloxy phosphorus monomers2
• Phosphorylation agent3

REFERENCES