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O-(Trimethylsilyl)hydroxylamine_Molecular_structure_CAS_22737-36-6)
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O-(Trimethylsilyl)hydroxylamine

Catalog No. 92776 Name Sigma Aldrich
CAS Number 22737-36-6 Website http://www.sigmaaldrich.com
M. F. C3H11NOSi Telephone 1-800-521-8956
M. W. 105.21104 Fax
Purity ≥90% (GC) Email
Storage Chembase ID: 88716

SYNONYMS

Title
O-(三甲基硅基)羟胺
IUPAC name
O-(trimethylsilyl)hydroxylamine
IUPAC Traditional name
O-(trimethylsilyl)hydroxylamine
Synonyms
氨氧基三甲基硅烷
Aminoxytrimethylsilane

DATABASE IDS

CAS Number 22737-36-6
MDL Number MFCD00010872
Beilstein Number 2035893

PROPERTIES

Grade technical
Impurities hexamethyl siloxane
Linear Formula (CH3)3SiONH2
Purity ≥90% (GC)
Boiling Point 98-100 °C(lit.)
Density 0.86 g/mL at 25 °C(lit.)
Flash Point 12 °C
Flash Point 53.6 °F
Refractive Index n20/D 1.405(lit.)
Refractive Index n20/D 1.405
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H225-H314
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P280-P305 + P351 + P338-P310
RID/ADR UN 2733 3/PG 2
Risk Statements 11-34
Safety Statements 16-26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 3
UN Number 2733
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
O-Protected hydroxylamine useful for the synthesis of N-substituted derivatives of hydroxylamine, e.g. N-(diphenylphosphinoyl)hydroxylamine1
Description (简体中文)
Other Notes
O-保护羟胺可用于合成羟胺的 N-取代衍生物,如 N-(二苯基膦酰基)羟胺1

REFERENCES