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Lithium aluminum hydride solution

Catalog No. 62424 Name Sigma Aldrich
CAS Number 16853-85-3 Website http://www.sigmaaldrich.com
M. F. AlLi Telephone 1-800-521-8956
M. W. 33.922538 Fax
Purity Email
Storage Chembase ID: 108633

SYNONYMS

Title
氢化铝锂 溶液
IUPAC name
lithium(1+) ion alumanuide
IUPAC Traditional name
lithium(1+) ion alumanuide
Synonyms
LAH
Lithium alanate
Lithium tetrahydroaluminate

DATABASE IDS

PubChem SID 24882217
MDL Number MFCD00011075
CAS Number 16853-85-3

PROPERTIES

Concentration ~2.3 M in THF
Grade purum
Linear Formula LiAlH4
Apperance suspension
Density 0.88 g/mL at 20 °C
Flash Point -17 °C
Flash Point 1.4 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H260-H314-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P223-P231 + P232-P261-P370 + P378-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-15-19-35-37
Safety Statements 16-26-36/37/39-43-45
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 1

DETAILS

Description (English)
Application
Reactant or reagent for:
• The preparation of thermoplastic polyester polyamides from oleic acid1
• Lithium-polymer batteries2
• Hydrodefluorination of gem-difluoromethylene derivatives3
• Asymmetric aldol reactions4
• Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties5LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols6
Description (简体中文)
Application
Reactant or reagent for:
• The preparation of thermoplastic polyester polyamides from oleic acid1
• Lithium-polymer batteries2
• Hydrodefluorination of gem-difluoromethylene derivatives3
• Asymmetric aldol reactions4
• Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties5LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols6

REFERENCES