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D-(-)-2,3-Butanediol_Molecular_structure_CAS_24347-58-8)
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D-(-)-2,3-Butanediol

Catalog No. 18965 Name Sigma Aldrich
CAS Number 24347-58-8 Website http://www.sigmaaldrich.com
M. F. C4H10O2 Telephone 1-800-521-8956
M. W. 90.121 Fax
Purity ≥96.0% (sum of enantiomers, GC) Email
Storage Chembase ID: 151261

SYNONYMS

Title
D-(-)-2,3-丁二醇
IUPAC name
(2R,3R)-butane-2,3-diol
IUPAC Traditional name
(R,R)-butane-2,3-diol
Synonyms
(R,R)-2,3-Butanediol
(R,R)-2,3-丁二醇

DATABASE IDS

CAS Number 24347-58-8
MDL Number MFCD00064267
EC Number 246-186-9
Beilstein Number 1718901

PROPERTIES

Empirical Formula (Hill Notation) C4H10O2
Grade purum
Optical Purity enantiomeric ratio: ~98:2 (GC)
Purity ≥96.0% (sum of enantiomers, GC)
Boiling Point 177-179 °C(lit.)
Density 0.992 g/mL at 20 °C(lit.)
Flash Point 85 °C
Flash Point 185 °F
Optical Rotation [α]20/D -13±1°, neat
Refractive Index n20/D 1.433
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Storage Temperature -20°C
German water hazard class 3

DETAILS

Description (English)
Other Notes
Chiral diol; used for determining the enantiomeric purity of ketones by acetal formation and 13C-NMR1,2; or chromatography3; Resolution of ketones4; Determination of enantiomeric purity of lactones by ortho esterification and GC5
Description (简体中文)
Other Notes
手性二醇;用于通过乙缩醛的形成和 13C-NMR1,2 测定酮的对映体纯度;或用于色谱分析3;用于酮的拆分4;用于通过邻位酯化反应和气相色谱法测定内酯的对映体纯度5

REFERENCES