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(-)-Di[(1R)-menthyl] fumarate_Molecular_structure_CAS_34675-24-6)
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(-)-Di[(1R)-menthyl] fumarate

Catalog No. 47965 Name Sigma Aldrich
CAS Number 34675-24-6 Website http://www.sigmaaldrich.com
M. F. C24H40O4 Telephone 1-800-521-8956
M. W. 392.572 Fax
Purity ≥94% (sum of enantiomers, HPLC) Email
Storage Chembase ID: 156772

SYNONYMS

Title
(-)-二[(1R)-薄荷基]富马酸酯
IUPAC name
(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl (1S,2R,5S)-5-methyl-2-(propan-2-yl)cyclohexyl but-2-enedioate
IUPAC Traditional name
(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl (1S,2R,5S)-2-isopropyl-5-methylcyclohexyl but-2-enedioate

DATABASE IDS

PubChem SID 24871637
CAS Number 34675-24-6
MDL Number MFCD00075423
Beilstein Number 2568525

PROPERTIES

Empirical Formula (Hill Notation) C24H40O4
Grade technical
Purity ≥94% (sum of enantiomers, HPLC)
Melting Point 62-64 °C
Optical Rotation [α]20/D -102±2°, c = 1% in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
Chiral dienophile for asymmetric DA cycloadditions1,2,3,4; Synthesis of menthyl glyoxylate by ox. cleavage5
Description (简体中文)
Other Notes
用于不对称 DA 环加成反应的手性亲二烯体1,2,3,4;通过氧化裂解合成薄荷基乙醛酸酯5

REFERENCES