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L-Cystine bisallyl ester di(p-toluenesulfonate) salt_Molecular_structure_CAS_142601-71-6)
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L-Cystine bisallyl ester di(p-toluenesulfonate) salt

Catalog No. 30230 Name Sigma Aldrich
CAS Number 142601-71-6 Website http://www.sigmaaldrich.com
M. F. C26H36N2O10S4 Telephone 1-800-521-8956
M. W. 664.83144 Fax
Purity ≥95.0% (sum of enantiomers, TLC) Email
Storage Chembase ID: 156768

SYNONYMS

Title
L-胱氨酸双烯丙酯 二(对甲苯磺酸) 盐
IUPAC name
bis(4-methylbenzene-1-sulfonic acid) prop-2-en-1-yl (2R)-2-amino-3-{[(2R)-2-amino-3-oxo-3-(prop-2-en-1-yloxy)propyl]disulfanyl}propanoate
IUPAC Traditional name
bis(toluenesulfonic acid) prop-2-en-1-yl (2R)-2-amino-3-{[(2R)-2-amino-3-oxo-3-(prop-2-en-1-yloxy)propyl]disulfanyl}propanoate

DATABASE IDS

Beilstein Number 7966375
CAS Number 142601-71-6
MDL Number MFCD00043424
PubChem SID 24858244

PROPERTIES

Linear Formula CH2=CHCH2OCOCH(NH2)CH2SSCH2CH(NH2)COOCH2CH=CH2.2C7H8O3S
Purity ≥95.0% (sum of enantiomers, TLC)
Melting Point 175-180 °C
Optical Rotation [α]20/D -11.5±1°, c = 3% in methanol
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
Used in peptide and N-glycopeptide synthesis; the ester is selectively deblocked with (Ph3P)3RhCl1
Packaging
10 g in glass bottle
Description (简体中文)
Other Notes
用于多肽和 N-糖肽的合成;通过 (Ph3P)3RhCl 进行酯的选择性脱封反应1
包装
10 g in glass bottle

REFERENCES