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1-(Trimethylsilyl)-1-pentyne_Molecular_structure_CAS_18270-17-2)
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1-(Trimethylsilyl)-1-pentyne

Catalog No. 92784 Name Sigma Aldrich
CAS Number 18270-17-2 Website http://www.sigmaaldrich.com
M. F. C8H16Si Telephone 1-800-521-8956
M. W. 140.29814 Fax
Purity ≥98.0% (GC) Email
Storage Chembase ID: 139925

SYNONYMS

Title
1-三甲基硅基-1-戊炔
IUPAC name
trimethyl(pent-1-yn-1-yl)silane
IUPAC Traditional name
trimethyl(pent-1-yn-1-yl)silane
Synonyms
1-戊炔-1-基三甲基硅烷
1-Pentyn-1-yltrimethylsilane

DATABASE IDS

CAS Number 18270-17-2
MDL Number MFCD00077890
Beilstein Number 1744218

PROPERTIES

Grade purum
Linear Formula CH3CH2CH2C≡CSi(CH3)3
Purity ≥98.0% (GC)
Boiling Point 135 °C(lit.)
Density 0.765 g/mL at 25 °C(lit.)
Flash Point 30 °C
Flash Point 86 °F
Refractive Index n20/D 1.425(lit.)
Refractive Index n20/D 1.427
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H226-H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 3
Risk Statements 10-36/37/38
Safety Statements 26-36
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Other Notes
Versatile derivative of 1-pentyne; SnCl4 and ZnCl2 catalyzed coupling with acetals1; Reaction with allyl-zinc compounds to cyclopentenes2
Description (简体中文)
Other Notes
1-戊炔的多功能衍生物;与缩醛发生 SnCl4 和 ZnCl2 催化偶联反应1;与烯丙基锌化合物反应生成环戊烯2

REFERENCES