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1-Trimethylsilyl-1-hexyne_Molecular_structure_CAS_3844-94-8)
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1-Trimethylsilyl-1-hexyne

Catalog No. 92783 Name Sigma Aldrich
CAS Number 3844-94-8 Website http://www.sigmaaldrich.com
M. F. C9H18Si Telephone 1-800-521-8956
M. W. 154.32472 Fax
Purity ≥98.0% (GC) Email
Storage Chembase ID: 146261

SYNONYMS

Title
1-三甲基硅基-1-己炔
IUPAC name
hex-1-yn-1-yltrimethylsilane
IUPAC Traditional name
hex-1-yn-1-yltrimethylsilane

DATABASE IDS

MDL Number MFCD00075407
CAS Number 3844-94-8
Beilstein Number 1421652

PROPERTIES

GHS Precautionary statements P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 3
Risk Statements 10-36/37/38
Safety Statements 26-36
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H226-H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Grade purum
Linear Formula CH3(CH2)3C≡CSi(CH3)3
Purity ≥98.0% (GC)
Boiling Point 65 °C/35 mmHg(lit.)
Density 0.764 g/mL at 25 °C(lit.)
Flash Point 50 °C
Flash Point 122 °F
Refractive Index n20/D 1.431(lit.)
Refractive Index n20/D 1.431

DETAILS

Description (English)
Other Notes
Versatile derivative of 1-hexyne; SnCl4 and ZnCl2 catalyzed coupling with acetals1; Reaction with allyl reagents to cyclopentanoids2,3
Description (简体中文)
Other Notes
1-己炔的多功能衍生物;与缩醛发生 SnCl4 和 ZnCl2 催化偶联反应1;与烯丙基试剂反应生成类环戊烷类物质2,3

REFERENCES