Tributyl(trimethylsilyl)stannane

• Catalog No.: 92781
• CAS Number: 17955-46-3
• M. F.: C15H36SiSn
• M. W.: 363.23284
• Purity: ≥97.0% (GC)

SYNONYMS

• Title: 三丁基（三甲基硅）锡烷
• IUPAC name: trimethyl(tributylstannyl)silane
• IUPAC Traditional name: trimethyl(tributylstannyl)silane
• Synonyms: (三丁基锡烷基)三甲基硅烷; (三甲基硅基)三丁基锡烷; (Tributylstannyl)trimethylsilane; (Trimethylsilyl)tributylstannane; (Trimethylsilyl)tributyltin; (三甲基硅基)三丁基锡

DATABASE IDS

• Beilstein Number: 4127163
• CAS Number: 17955-46-3
• MDL Number: MFCD00054903

PROPERTIES

• Grade: purum
• Linear Formula: [CH3(CH2)3]3SnSi(CH3)3
• Purity: ≥97.0% (GC)
• Boiling Point: 102-103 °C/0.5 mmHg(lit.)
• Density: 1.04 g/mL at 25 °C(lit.)
• Flash Point: 113 °C
• Flash Point: 235.4 °F
• Refractive Index: n20/D 1.488(lit.)
• Refractive Index: n20/D 1.488
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H312-H315-H319-H372-H410
• European Hazard Symbols: Toxic (T)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P273-P280-P301 + P310-P305 + P351 + P338-P314-P501
• RID/ADR: UN 2788 6.1/PG 3
• Risk Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 36/37/39-45-60-61
• Hazard Class: 6.1
• UN Number: 2788
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Reagent undergoing cis-addition to terminal acetylenes with tin at the internal position1; Generation of tributylstannyl anions2,3,4

Description (简体中文)

Other Notes
可顺式加成到末端炔烃上，其中锡位于内部位点1；生成三丁基锡烷基阴离子2,3,4