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Diethylaluminum cyanide solution_Molecular_structure_CAS_5804-85-3)
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Diethylaluminum cyanide solution

Catalog No. 36789 Name Sigma Aldrich
CAS Number 5804-85-3 Website http://www.sigmaaldrich.com
M. F. C5H10AlN Telephone 1-800-521-8956
M. W. 111.121138 Fax
Purity Email
Storage Chembase ID: 138632

SYNONYMS

Title
二乙基氰化铝 溶液
IUPAC name
diethylalumanecarbonitrile
IUPAC Traditional name
diethylaluminium cyanide

DATABASE IDS

CAS Number 5804-85-3
Beilstein Number 3587410
MDL Number MFCD00001764
PubChem SID 24862858

PROPERTIES

Concentration ~1 M in toluene
Grade technical
Linear Formula (C2H5)2AlCN
Density 0.87 g/mL at 20 °C
Flash Point 7 °C
Flash Point 44.6 °F
GHS Pictograms GHS02
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H225-H300-H304-H311-H315-H330-H336-H361d-H373-H400
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Highly toxic Highly toxic (T+)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P260-P264-P273-P280-P284
RID/ADR UN 3123 6.1/PG 1
Risk Statements 63-11-26/27/28-32-38-48/20-50/53-65
Safety Statements 16-28-36/37-45-61-62
Supplemental Hazard Statements Contact with acids liberates very toxic gas.
Hazard Class 6.1
UN Number 3123
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Other Notes
Reagent for selective transformations of ketones into cyanohydrines1,2; Selective opening of epoxides and other oxygen heterocycles into cyanohydrines3,4; Preparation of glycosyl cyanides from bromides5
Description (简体中文)
Other Notes
用于酮的选择性转化生成氰醇1,2;环氧化物和其他氧杂环化合物的选择性开环生成氰醇3,4;由溴化物制备糖基氰化物的试剂5

REFERENCES