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D-tert-Leucine_Molecular_structure_CAS_26782-71-8)
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D-tert-Leucine

Catalog No. 61835 Name Sigma Aldrich
CAS Number 26782-71-8 Website http://www.sigmaaldrich.com
M. F. C6H13NO2 Telephone 1-800-521-8956
M. W. 131.17292 Fax
Purity ≥99.0% (NT) Email
Storage Chembase ID: 69899

SYNONYMS

Title
D-叔亮氨酸
IUPAC name
(2R)-2-amino-3,3-dimethylbutanoic acid
IUPAC Traditional name
(2R)-2-amino-3,3-dimethylbutanoic acid
Synonyms
D-α-tert-Butylglycine
(R)-2-氨基-3,3-二甲基丁酸
(R)-2-Amino-3,3-dimethylbutyric acid
D-α-叔丁基甘氨酸

DATABASE IDS

CAS Number 26782-71-8
Beilstein Number 1721825
PubChem SID 24874860
MDL Number MFCD00004265

PROPERTIES

Grade puriss.
Impurities ~0.5% water
Linear Formula (CH3)3CCH(NH2)CO2H
Purity ≥99.0% (NT)
Melting Point ≥300 °C(lit.)
Optical Rotation [α]20/D -7±1°, c = 5% in 5 M HCl
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
Unnatural, "fat" amino acid 1; chiral auxiliary, e.g. in the synthesis of aldehydes by double alkylation of unsaturated aldimines of tert-Leu esters 2,3; Synthesis of amino acids4
Description (简体中文)
Other Notes
非天然,脂肪族氨基酸1;手性助剂,例如用于经叔亮氨酸酯不饱和亚胺醛的双烷基化合成醛的反应2,3;氨基酸的合成4

REFERENCES