Bromo-tert-butyl(methoxy)phenylsilane

• Catalog No.: 20240
• CAS Number: 94124-39-7
• M. F.: C11H17BrOSi
• M. W.: 273.24158
• Purity: ≥95.0% (GC)

SYNONYMS

• Title: 溴-叔丁基(甲氧基)苯基硅烷
• IUPAC name: bromo(tert-butyl)methoxy(phenyl)silane
• IUPAC Traditional name: bromo(tert-butyl)methoxy(phenyl)silane
• Synonyms: TBMPSiBr; tert-Butyl(methoxy)phenylbromosilane; 叔丁基(甲氧基)苯基溴硅烷

DATABASE IDS

• PubChem SID: 24852061
• MDL Number: MFCD00043308
• Beilstein Number: 4983916
• CAS Number: 94124-39-7

PROPERTIES

• Empirical Formula (Hill Notation): C11H17BrOSi
• Purity: ≥95.0% (GC)
• Boiling Point: 80-82 °C/0.1 mmHg
• Density: 1.218 g/mL at 20 °C(lit.)
• Flash Point: 106 °C
• Flash Point: 222.8 °F
• Refractive Index: n20/D 1.516
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 3265 8/PG 2
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45
• Hazard Class: 8
• UN Number: 3265
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Protecting group reagent for alcohols; derivatives are selectively cleaved with fluoride in the presence of other silyl ethers1,2

Description (简体中文)

Other Notes
醇的保护基团试剂；在其他硅醚存在的条件下，其衍生物可与氟化物发生选择性裂解反应1,2