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N,N-Dimethylmethyleneiminium iodide_Molecular_structure_CAS_33797-51-2)
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N,N-Dimethylmethyleneiminium iodide

Catalog No. 40769 Name Sigma Aldrich
CAS Number 33797-51-2 Website http://www.sigmaaldrich.com
M. F. C3H8IN Telephone 1-800-521-8956
M. W. 185.00679 Fax
Purity ≥95.0% (AT) Email
Storage Chembase ID: 127300

SYNONYMS

Title
N,N-二甲基亚甲基碘化铵
IUPAC name
dimethyl(methylidene)azanium iodide
IUPAC Traditional name
dimethyl(methylidene)azanium iodide
Synonyms
N,N-Dimethylmethyleneammonium iodide
Eschenmoser 盐
Eschenmoser’s salt
N,N-二甲基亚甲基碘化胺

DATABASE IDS

MDL Number MFCD00011810
PubChem SID 24865478
Beilstein Number 1731022
CAS Number 33797-51-2
EC Number 251-680-2

PROPERTIES

Grade purum
Linear Formula CH2=N+(CH3)2I-
Purity ≥95.0% (AT)
Melting Point 219 °C (dec.)(lit.)
Melting Point 235-240 °C (dec.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Other Notes
"Mannich-reagent" for direct use1,2,3,4: α-methylenation of carbonyls and ene reactions with olefins
Description (简体中文)
Other Notes
供直接使用的"Mannich 试剂"1,2,3,4:羰基的 α-亚甲基化作用以及与烯烃进行烯反应

REFERENCES