Dimethyl (1S,9S)-5-cyanosemicorrin-1,9-dicarboxylate

• Catalog No.: 28600
• CAS Number: 105251-49-8
• M. F.: C14H17N3O4
• M. W.: 291.30248
• Purity: ≥95.0% (sum of enantiomers, HPLC)

SYNONYMS

• Title: (1S,9S)-5-氰基半咕啉-1,9-二羧酸二甲酯
• IUPAC name: methyl (2S)-5-{cyano[(5S)-5-(methoxycarbonyl)pyrrolidin-2-ylidene]methyl}-3,4-dihydro-2H-pyrrole-2-carboxylate
• IUPAC Traditional name: methyl (2S)-5-{cyano[(5S)-5-(methoxycarbonyl)pyrrolidin-2-ylidene]methyl}-3,4-dihydro-2H-pyrrole-2-carboxylate
• Synonyms: Semicorrin chiral ligand 1; 半咕啉手性配体 1

DATABASE IDS

• MDL Number: MFCD00144132
• CAS Number: 105251-49-8
• PubChem SID: 24857227
• Beilstein Number: 5110296

PROPERTIES

• Empirical Formula (Hill Notation): C14H17N3O4
• Grade: purum
• Purity: ≥95.0% (sum of enantiomers, HPLC)
• Melting Point: 77-79 °C(lit.)
• Melting Point: 77-79 °C
• Optical Rotation: [α]20/D -145±2°, c = 1% in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Starting material for the preparation of various chiral bis(semicorrinato) Cu(II) and Co(II) catalysts1,2,3

Description (简体中文)

Other Notes
制备各种手性双(半咕啉)铜(II) 和钴(II) 催化剂的原料1,2,3