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2-Chloro-1,3,2-benzodioxaphosphorin-4-one_Molecular_structure_CAS_5381-99-7)
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2-Chloro-1,3,2-benzodioxaphosphorin-4-one

Catalog No. 23514 Name Sigma Aldrich
CAS Number 5381-99-7 Website http://www.sigmaaldrich.com
M. F. C7H4ClO3P Telephone 1-800-521-8956
M. W. 202.531621 Fax
Purity ≥95.0% (AT) Email
Storage Chembase ID: 87888

SYNONYMS

Title
2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮
IUPAC name
2-chloro-2,4-dihydro-1,3,2-benzodioxaphosphinin-4-one
IUPAC Traditional name
2-chloro-1,3,2-benzodioxaphosphinin-4-one
Synonyms
Salicyl chlorophosphite

DATABASE IDS

CAS Number 5381-99-7
PubChem SID 24854081
Beilstein Number 1311951
MDL Number MFCD00013353

PROPERTIES

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 1
Risk Statements 14-34
Safety Statements 26-36/37/39-43-45-Neverusewater.
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 3261
Packing Group 1
German water hazard class 3
Empirical Formula (Hill Notation) C7H4ClO3P
Grade purum
Purity ≥95.0% (AT)
Boiling Point 127-128 °C/11 mmHg(lit.)
Flash Point 113 °C
Flash Point 235.4 °F
Melting Point 36-40 °C(lit.)

DETAILS

Description (English)
Other Notes
Phosphitylating agent for nucleosides and carbohydrates1,2,3; Synthesis of triphosphates and 1-thiotriphosphates from alcohols4
Description (简体中文)
Other Notes
用于核苷和碳水化合物的亚磷酸化剂1,2,3;由醇合成三磷酸酯和 1-硫代三磷酸酯4

REFERENCES