Triethylborane solution

• Catalog No.: 90369
• CAS Number: 97-94-9
• M. F.: C6H15B
• M. W.: 97.9943

SYNONYMS

• Title: 三乙基硼 溶液
• IUPAC name: triethylborane
• IUPAC Traditional name: triethylborane

DATABASE IDS

• MDL Number: MFCD00009022
• Beilstein Number: 1731462
• CAS Number: 97-94-9

PROPERTIES

• Concentration: ~15% in hexane
• Grade: purum
• Linear Formula: (C2H5)3B
• Density: 0.675 g/mL at 20 °C
• Refractive Index: n20/D 1.380
• GHS Signal Word: Danger
• GHS Hazard statements: H250-H261-H302-H304-H314-H336-H361f-H373-H411
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P222-P231 + P232-P261-P273-P280-P422
• RID/ADR: UN 3399 4.3/PG 2
• Risk Statements: 17-34-48/20-51/53-62-65-67
• Safety Statements: 26-36/37/39-45-61-62
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6

Description (简体中文)

Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6