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tert-Butyldimethylsilyl trifluoromethanesulfonate_Molecular_structure_CAS_69739-34-0)
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tert-Butyldimethylsilyl trifluoromethanesulfonate

Catalog No. 91742 Name Sigma Aldrich
CAS Number 69739-34-0 Website http://www.sigmaaldrich.com
M. F. C7H15F3O3SSi Telephone 1-800-521-8956
M. W. 264.3379096 Fax
Purity ≥98.0% (T) Email
Storage Chembase ID: 94317

SYNONYMS

Title
叔丁基二甲基硅基三氟甲磺酸酯
IUPAC name
tert-butyldimethylsilyl trifluoromethanesulfonate
IUPAC Traditional name
tert-butyldimethylsilyl trifluoromethanesulfonate
Synonyms
Trifluoromethanesulfonic acid tert-butyldimethylsilylester
三氟甲磺酸叔丁基二甲基硅基酯
TBDMS 三氟甲磺酸酯
TBDMS triflate

DATABASE IDS

Beilstein Number 2370068
CAS Number 69739-34-0
PubChem SID 24889549
MDL Number MFCD00000405
EC Number 274-102-0

PROPERTIES

Grade purum
Linear Formula CF3SO3Si(CH3)2C(CH3)3
Purity ≥98.0% (T)
Boiling Point 65-67 °C/12 mmHg(lit.)
Density 1.151 g/mL at 25 °C(lit.)
Flash Point 37 °C
Flash Point 98.6 °F
Refractive Index n20/D 1.385(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H226-H314-H335
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34-37
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Powerful and strongly electrophilic reagent for the introduction of the tert-butyl-dimethylsilyl group1,2,3,4; Reviews5
Description (简体中文)
Other Notes
有效的强亲电试剂,用于引入叔丁基二甲基硅基1,2,3,4;综述5

REFERENCES