4-Methoxybenzyl chloride

• Catalog No.: 64870
• CAS Number: 824-94-2
• M. F.: C8H9ClO
• M. W.: 156.60946
• Purity: ≥97.0% (GC)

SYNONYMS

• Title: 4-甲氧基氯苄
• IUPAC name: 1-(chloromethyl)-4-methoxybenzene
• IUPAC Traditional name: 4-methoxybenzyl chloride
• Synonyms: 4-(Chloromethyl)anisole; 4-(氯甲基)苯甲醚

DATABASE IDS

• Beilstein Number: 606667
• PubChem SID: 24883599
• MDL Number: MFCD00000915
• EC Number: 212-540-6
• CAS Number: 824-94-2

PROPERTIES

• Contains: 1% potassium carbonate as stabilizer
• Grade: purum
• Impurities: bottom sediment (K2CO3)
• Linear Formula: CH3OC6H4CH2Cl
• Purity: ≥97.0% (GC)
• Boiling Point: 117-118 °C/14 mmHg(lit.)
• Density: 1.155 g/mL at 25 °C(lit.)
• Flash Point: 109 °C
• Flash Point: 228.2 °F
• Melting Point: -1 °C(lit.)
• Refractive Index: n20/D 1.548(lit.)
• Refractive Index: n20/D 1.548
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 3265 8/PG 3
• Risk Statements: 34
• Safety Statements: 26-27-36/37/39-45
• Storage Temperature: 2-8°C
• Hazard Class: 8
• UN Number: 3265
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Protecting group reagent for alcohols; the ethers are cleaved hydrogenolytically as well as oxidatively with DDQ or ceric ammonium nitrate, CAN1,2

Description (简体中文)

Other Notes
醇的保护基团试剂；此类醚在 DDQ 或硝酸铈铵 (CAN) 存在下发生氢化裂解以及氧化裂解1,2