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Methyl trifluoromethanesulfonate

Catalog No. 91736 Name Sigma Aldrich
CAS Number 333-27-7 Website http://www.sigmaaldrich.com
M. F. C2H3F3O3S Telephone 1-800-521-8956
M. W. 164.1036296 Fax
Purity ≥97.0% (GC) Email
Storage Chembase ID: 8489

SYNONYMS

Title
三氟甲磺酸甲酯
IUPAC name
methyl trifluoromethanesulfonate
IUPAC Traditional name
triflate ester
Synonyms
Methyl triflate
三氟甲基磺酸甲酯

DATABASE IDS

Beilstein Number 774772
EC Number 206-371-7
MDL Number MFCD00000409
CAS Number 333-27-7

PROPERTIES

Grade purum
Linear Formula CF3SO2OCH3
Purity ≥97.0% (GC)
Boiling Point 94-99 °C(lit.)
Density 1.45 g/mL at 25 °C(lit.)
Flash Point 38 °C
Flash Point 100 °F
Refractive Index n20/D 1.326(lit.)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Extremely reactive methylating agent which is about 104 to 105 more reactive than methyl tosylate and methyl iodide1,2; review3; O-methylation of carbohydrates4; N-methylation of amino acids5
Description (简体中文)
Other Notes
极其活泼的甲基化试剂,活性比甲苯磺酸甲酯和甲基碘高约 104 至 105 倍1,2;综述3;糖的 O-甲基化反应4;氨基酸的 N-甲基化反应5

REFERENCES