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1,6-Anhydro-β-D-glucose_Molecular_structure_CAS_498-07-7)
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1,6-Anhydro-β-D-glucose

Catalog No. 10390 Name Sigma Aldrich
CAS Number 498-07-7 Website http://www.sigmaaldrich.com
M. F. C6H10O5 Telephone 1-800-521-8956
M. W. 162.1406 Fax
Purity ≥98.0% (TLC) Email
Storage Chembase ID: 89302

SYNONYMS

Title
1,6-脱水-β-D-葡萄糖
IUPAC name
(1R,2S,3S,4R,5R)-6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol
IUPAC Traditional name
levoglucosan
Synonyms
Levoglucosan
左旋葡聚糖

DATABASE IDS

Beilstein Number 80998
PubChem SID 24846629
EC Number 207-855-0
CAS Number 498-07-7
MDL Number MFCD00063248

PROPERTIES

Empirical Formula (Hill Notation) C6H10O5
Grade purum
Purity ≥98.0% (TLC)
Melting Point 173-183 °C
Melting Point 182-184 °C(lit.)
Optical Rotation [α]20/D -66±2°, c = 10% in H2O
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Other Notes
Important carbohydrate derivative with interesting chemical reactivity arising from its rigid bicyclic framework. Derivatisations proceed selectively to give the 2,4-disubstituted levoglucosan, reviews1,2; 1,6:2,3-Dianhydro-β-D-mannopyranose3,4
Description (简体中文)
Other Notes
重要的碳水化合物衍生物,因其稳定的双环体系产生的化学反应性而备受关注。衍生化反应可选择性地生成 2,4-二取代的左旋葡聚糖,综述1,2;1,6:2,3-二去水-β-D-吡喃甘露糖3,4

REFERENCES