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2-Bromo-1,3,2-benzodioxaborole_Molecular_structure_CAS_51901-85-0)
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2-Bromo-1,3,2-benzodioxaborole

Catalog No. 16310 Name Sigma Aldrich
CAS Number 51901-85-0 Website http://www.sigmaaldrich.com
M. F. C6H4BBrO2 Telephone 1-800-521-8956
M. W. 198.80976 Fax
Purity ≥97.0% (AT) Email
Storage Chembase ID: 146930

SYNONYMS

Title
B-溴-1,2-苯二酚硼烷
IUPAC name
2-bromo-2H-1,3,2-benzodioxaborole
IUPAC Traditional name
2-bromo-1,3,2-benzodioxaborole
Synonyms
B-Bromocatechol-borane
B-溴邻苯二酚硼烷

DATABASE IDS

PubChem SID 24850023
CAS Number 51901-85-0
MDL Number MFCD00013341
Beilstein Number 2445073

PROPERTIES

Empirical Formula (Hill Notation) C6H4BBrO2
Grade purum
Purity ≥97.0% (AT)
Shipped in wet ice
Boiling Point 76 °C/9 mmHg(lit.)
Flash Point 42 °C
Flash Point 107.6 °F
Melting Point 51-53 °C(lit.)
Melting Point 51-53 °C
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H228-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P210-P280-P305 + P351 + P338-P310
RID/ADR UN 2925 4.1/PG 2
Risk Statements 14-34-37
Safety Statements 26-36/37/39-45
Storage Temperature -20°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.1
UN Number 2925
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Reagent for the selective cleavage of ethers, esters and carbamates1,2
Description (简体中文)
Other Notes
用于醚、酯和氨基甲酸酯选择性裂解的试剂1,2

REFERENCES