Tris(triphenylphosphine)rhodium(I) chloride

• Catalog No.: 93403
• CAS Number: 14694-95-2
• M. F.: C54H45ClP3Rh
• M. W.: 925.214883
• Purity: ≥97.0% (CH)

SYNONYMS

• Title: 三(三苯基膦)氯化铑(I)
• IUPAC name: chlororhodium; tris(triphenylphosphane)
• IUPAC Traditional name: chlororhodium; tris(triphenylphosphine)
• Synonyms: Wilkinson 催化剂; RhCl(PPh3)3; Wilkinson’s catalyst; NSC 124140; Rhodium(I) tris(triphenylphosphine) chloride; 三(三苯膦基)氯化铑(I)

DATABASE IDS

• PubChem SID: 24889752
• Beilstein Number: 4581440
• MDL Number: MFCD00010016
• EC Number: 238-744-5
• CAS Number: 14694-95-2

PROPERTIES

• Grade: purum
• Linear Formula: [(C6H5)3P]3RhCl
• Purity: ≥97.0% (CH)
• Melting Point: 245-250 °C (dec.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Application
Hydrosilylation CatalystsCatalyst used for many organic reactions including:
• Chemoselective allylic alkylations1
• Stoichiometric activation of Si-H bonds2 and hydrosilylations3
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst4
• Polymerization of diorganostannanes5

Description (简体中文)

Application
Hydrosilylation CatalystsCatalyst used for many organic reactions including:
• Chemoselective allylic alkylations1
• Stoichiometric activation of Si-H bonds2 and hydrosilylations3
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst4
• Polymerization of diorganostannanes5