Home > Compound List > Product Information
(R)-4-Isopropyl-2-oxazolidinethione_Molecular_structure_CAS_1217463-35-8)
Click picture or here to close

(R)-4-Isopropyl-2-oxazolidinethione

Catalog No. 08914 Name Sigma Aldrich
CAS Number 1217463-35-8 Website http://www.sigmaaldrich.com
M. F. C6H11NOS Telephone 1-800-521-8956
M. W. 145.22264 Fax
Purity ≥95.0% (HPLC) Email
Storage Chembase ID: 77297

SYNONYMS

Title
(R)-4-异丙基-2-噁唑烷硫酮
IUPAC name
(4R)-4-(propan-2-yl)-1,3-oxazolidine-2-thione
IUPAC Traditional name
(4R)-4-isopropyl-1,3-oxazolidine-2-thione

DATABASE IDS

PubChem SID 24846234
MDL Number MFCD06658218
CAS Number 1217463-35-8

PROPERTIES

Empirical Formula (Hill Notation) C6H11NOS
Optical Purity enantiomeric ratio: ≥99:1 (HPLC)
Purity ≥95.0% (HPLC)
Melting Point 48-52 °C
Optical Rotation [α]/D +22±2°, c = 0.4 in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
A highly selective and efficient chiral auxiliary1 which can be directly reduced to its corresponding aldehyde and the chiral auxiliary by reductive cleavage with diisobutylaluminum hydride.2
Evans-Type Oxazolidinethione And Thiazolidinethione Auxiliaries
Description (简体中文)
Application
具有高度选择性和有效性的手性助剂1,与二异丁基氢化铝发生还原裂解反应可直接还原为相应的醛和手性助剂。2
Evans-Type Oxazolidinethione And Thiazolidinethione Auxiliaries

REFERENCES