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Diethyl methylphosphonate_Molecular_structure_CAS_683-08-9)
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Diethyl methylphosphonate

Catalog No. 64261 Name Sigma Aldrich
CAS Number 683-08-9 Website http://www.sigmaaldrich.com
M. F. C5H13O3P Telephone 1-800-521-8956
M. W. 152.128681 Fax
Purity ≥97.0% (GC) Email
Storage Chembase ID: 74936

SYNONYMS

Title
甲基膦酸二乙酯
IUPAC name
diethyl methylphosphonate
IUPAC Traditional name
diethyl methylphosphonate
Synonyms
DEMP
Bis(diethoxyphosphinyl)methane
双(二乙氧基氧膦基)甲烷
Diethoxymethylphosphine oxide

DATABASE IDS

PubChem SID 24883208
CAS Number 683-08-9
MDL Number MFCD00009813
Beilstein Number 1753416
EC Number 211-667-4

PROPERTIES

Grade purum
Linear Formula CH3P(O)(OC2H5)2
Purity ≥97.0% (GC)
Boiling Point 194 °C(lit.)
Density 1.041 g/mL at 25 °C(lit.)
Flash Point 75 °C
Flash Point 167 °F
Refractive Index n20/D 1.414(lit.)
Refractive Index n20/D 1.414
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
RTECS SZ9085000
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Reactant for the synthesis of:
• Fluoroalkyl α- and β-aminophosphonates1
• Acyclic nucleoside phosphonates with branched phosphonoethoxy-Et chains as potential antivirals2
• Difluoromethyl arylphosphonates3
• Pyridone alkaloids with neuritogenic activity4
• Lipophilic meropenem-derived prodrugs5
• Phomactin cyclohexane core and diterpenoid framework6
• Phosphonylated peptides via solid-phase synthesis7
Description (简体中文)
Application
Reactant for the synthesis of:
• Fluoroalkyl α- and β-aminophosphonates1
• Acyclic nucleoside phosphonates with branched phosphonoethoxy-Et chains as potential antivirals2
• Difluoromethyl arylphosphonates3
• Pyridone alkaloids with neuritogenic activity4
• Lipophilic meropenem-derived prodrugs5
• Phomactin cyclohexane core and diterpenoid framework6
• Phosphonylated peptides via solid-phase synthesis7

REFERENCES