(R)-4-Benzyl-2-oxazolidinone

• Catalog No.: 13615
• CAS Number: 102029-44-7
• M. F.: C10H11NO2
• M. W.: 177.19984
• Purity: ≥99.5% (sum of enantiomers, GC)

SYNONYMS

• Title: (R)-4-苄基-2-噁唑烷酮
• IUPAC name: (4R)-4-benzyl-1,3-oxazolidin-2-one
• IUPAC Traditional name: (4R)-4-benzyl-1,3-oxazolidin-2-one

DATABASE IDS

• MDL Number: MFCD00010846
• Beilstein Number: 4782551
• CAS Number: 102029-44-7
• PubChem SID: 24848261

PROPERTIES

• Empirical Formula (Hill Notation): C10H11NO2
• Grade: puriss.
• Purity: ≥99.5% (sum of enantiomers, GC)
• Melting Point: 86-88 °C
• Optical Rotation: [α]20/D +63±2°, c = 1% in chloroform
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
The N-acyl derivatives are used in many enantioselective reactions: aldol reactions with carbonyl compounds. It gives higher yields than other auxiliaries;1 alkylation and Michael reaction;2,3 DA-cycloadditions of 3-acrylates.4

Description (简体中文)

Other Notes
这种 N-芳基衍生物可用于很多对映选择性反应：与羰基化合物的羟醛反应。比使用其他助剂的反应具有更高的产量；1烷基化反应和 Michael 反应；2,3与 3-丙烯酸酯的 DA-环加成反应。4