(-)-10,2-Camphorsultam

• Catalog No.: 21372
• CAS Number: 94594-90-8
• M. F.: C10H17NO2S
• M. W.: 215.31248
• Purity: ≥98.0% (GC)

SYNONYMS

• Title: (-)-10,2-樟脑磺内酰胺
• IUPAC name: (1S,5R,7R)-10,10-dimethyl-3λ^6-thia-4-azatricyclo[5.2.1.0^1,^5]decane-3,3-dione
• IUPAC Traditional name: (1S,5R,7R)-10,10-dimethyl-3λ^6-thia-4-azatricyclo[5.2.1.0^1,^5]decane-3,3-dione
• Synonyms: (-)-exo-10,2-Bornanesultam; (1S,5R)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸烷-3,3-二氧化物; (-)-exo-10,2-莰烷磺内酰胺; (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide

DATABASE IDS

• PubChem SID: 24852794
• MDL Number: MFCD00066271
• Beilstein Number: 83811
• CAS Number: 94594-90-8

PROPERTIES

• Empirical Formula (Hill Notation): C10H17NO2S
• Grade: purum
• Purity: ≥98.0% (GC)
• Melting Point: 183-185 °C
• Optical Rotation: [α]20/D -33±1°, c = 1% in ethanol
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Chiral auxiliary used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions 1; and for other asymmetric transformations 2,3

Description (简体中文)

Other Notes
用于制备 N-丙烯酰基衍生物的手性助剂，这种衍生物在不对称 Diels-Alder 反应中作为亲二烯体1；也可用于其他不对称转化2,3