N,O-Bis(trimethylsilyl)hydroxylamine

• Catalog No.: 15233
• CAS Number: 22737-37-7
• M. F.: C6H19NOSi2
• M. W.: 177.39216
• Purity: ≥97.0% (GC)

SYNONYMS

• Title: N,O-双(三甲基硅基)羟胺
• IUPAC name: 2,2,5,5-tetramethyl-3-oxa-4-aza-2,5-disilahexane
• IUPAC Traditional name: 2,2,5,5-tetramethyl-3-oxa-4-aza-2,5-disilahexane

DATABASE IDS

• EC Number: 245-188-7
• Beilstein Number: 1920452
• CAS Number: 22737-37-7
• MDL Number: MFCD00008266

PROPERTIES

• Grade: purum
• Linear Formula: (CH3)3SiONHSi(CH3)3
• Purity: ≥97.0% (GC)
• Boiling Point: 78-80 °C/100 mmHg(lit.)
• Density: 0.83 g/mL at 25 °C(lit.)
• Flash Point: 29 °C
• Flash Point: 84.2 °F
• Refractive Index: n20/D 1.411(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 2920 8/PG 2
• Risk Statements: 10-34
• Safety Statements: 26-36/37/39-45
• Storage Temperature: 2-8°C
• Hazard Class: 8
• UN Number: 2920
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Reagent for the synthesis of O-silylated hydroxamates which can be transformed into isocyanates 1; Synthesis of oximes from carbonyl compounds2; Reagent for electrophilic amination3; Reagent for nucleophilic hydroxylamination4

Description (简体中文)

Other Notes
用于合成 O-硅基化异羟肟酸酯的试剂，O-硅基化异羟肟酸酯可转化为异氰酸酯1；用于从羰基化合物合成肟的试剂2；用于亲电氨基化反应的试剂3；用于亲核羟胺化反应的试剂4