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Trimethylsilyl chlorosulfonate_Molecular_structure_CAS_4353-77-9)
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Trimethylsilyl chlorosulfonate

Catalog No. 26393 Name Sigma Aldrich
CAS Number 4353-77-9 Website http://www.sigmaaldrich.com
M. F. C3H9ClO3SSi Telephone 1-800-521-8956
M. W. 188.70526 Fax
Purity ≥99.0% (AT) Email
Storage Chembase ID: 147840

SYNONYMS

Title
三甲基硅基氯磺酸酯
IUPAC name
trimethylsilyl chloranesulfonate
IUPAC Traditional name
trimethylsilyl chloranesulfonate

DATABASE IDS

Beilstein Number 1763675
PubChem SID 24855895
MDL Number MFCD00040471
EC Number 224-425-8
CAS Number 4353-77-9

PROPERTIES

Grade purum
Linear Formula ClSO3Si(CH3)3
Purity ≥99.0% (AT)
Boiling Point 168-169 °C(lit.)
Boiling Point 62-64 °C/10 mmHg(lit.)
Density 1.225 g/mL at 25 °C(lit.)
Flash Point 42 °C
Flash Point 107.6 °F
Melting Point -26 °C(lit.)
Refractive Index n20/D 1.424(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Versatile sulfonation reagent1,2,3; For a simple preparation of the pyridine SO3 and the THF-SO3 adduct4
Description (简体中文)
Other Notes
多功能磺化剂1,2,3;吡啶 SO3 和 THF-SO3 加合物的简单制备4

REFERENCES