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(1S)-(+)-Camphor-10-sulfonyl chloride_Molecular_structure_CAS_21286-54-4)
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(1S)-(+)-Camphor-10-sulfonyl chloride

Catalog No. 21380 Name Sigma Aldrich
CAS Number 21286-54-4 Website http://www.sigmaaldrich.com
M. F. C10H15ClO3S Telephone 1-800-521-8956
M. W. 250.7423 Fax
Purity ≥99.0% (AT) Email
Storage Chembase ID: 149950

SYNONYMS

Title
(1S)-(+)-樟脑-10-磺酰氯
IUPAC name
[(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl]methanesulfonyl chloride
IUPAC Traditional name
[(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl]methanesulfonyl chloride
Synonyms
(+)-10-樟脑磺酸氯
(+)-Camphor-10-sulfonic acid chloride

DATABASE IDS

PubChem SID 24852805
Beilstein Number 3205974
CAS Number 21286-54-4
MDL Number MFCD00064156
EC Number 244-314-8

PROPERTIES

Empirical Formula (Hill Notation) C10H15ClO3S
Grade for chiral derivatization
Purity ≥99.0% (AT)
Purity ≥99.0%
Melting Point 67-68 °C
Optical Rotation [α]20/D +32±1°, c = 1% in chloroform
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 8
UN Number 3261
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Reagent used for the resolution of various types of compounds. Determination of enantiomeric purity of amines by derivatization and HPLC 1; Determination of enantiomeric purity of alcohols and amines by derivatization and H-NMR2,3; Reagent used for the simultaneous resolution and activation of alcohols 4
Description (简体中文)
Other Notes
用于多种类型化合物拆分的试剂。通过衍生化 HPLC 法测定胺的对映体纯度1;通过衍生化 H-NMR 法测定醇和胺的对映体纯度2,3;用于同时分离和活化醇的试剂4

REFERENCES