Hydroquinidine 4-methyl-2-quinolyl ether

• Catalog No.: 53952
• CAS Number: 135042-89-6
• M. F.: C30H33N3O2
• M. W.: 467.60192
• Purity: ≥95.0% (sum of enantiomers, TLC)

SYNONYMS

• Title: 氢化奎尼定 4-甲基-2-喹啉甲醚
• IUPAC name: 4-[(S)-[(2R,4S,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl][(4-methylquinolin-2-yl)oxy]methyl]-6-methoxyquinoline
• IUPAC Traditional name: 4-[(S)-[(2R,4S,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl][(4-methylquinolin-2-yl)oxy]methyl]-6-methoxyquinoline

DATABASE IDS

• MDL Number: MFCD00134563
• CAS Number: 135042-89-6
• Beilstein Number: 4830466

PROPERTIES

• Empirical Formula (Hill Notation): C30H33N3O2
• Grade: purum
• Purity: ≥95.0% (sum of enantiomers, TLC)
• Melting Point: 151-153 °C(lit.)
• Melting Point: 153-156 °C
• Optical Rotation: [α]20/D -168±3°, c = 1% in ethanol
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Catalyst used in the asymmetric dihydroxylation of olefins; it gives higher enantioselectivities than other derivatives of hydroquinidine, especally with terminal olefins1,2

Description (简体中文)

Other Notes
用于烯烃不对称双羟基化的催化剂；比氢化奎尼定的其他衍生物，尤其是末端烯烃的对映选择性更高1,2