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Methyl 2-(bromomethyl)acrylate

Catalog No. 17553 Name Sigma Aldrich
CAS Number 4224-69-5 Website http://www.sigmaaldrich.com
M. F. C5H7BrO2 Telephone 1-800-521-8956
M. W. 179.01188 Fax
Purity ≥95.0% (GC) Email
Storage Chembase ID: 149343

SYNONYMS

Title
2-(溴甲基)丙烯酸甲酯
IUPAC name
methyl 2-(bromomethyl)prop-2-enoate
IUPAC Traditional name
methyl 2-(bromomethyl)prop-2-enoate

DATABASE IDS

MDL Number MFCD00011697
CAS Number 4224-69-5
PubChem SID 24850506
Beilstein Number 1852481

PROPERTIES

Grade purum
Linear Formula H2C=C(CH2Br)CO2CH3
Purity ≥95.0% (GC)
Boiling Point 35-37 °C/1.3 mmHg(lit.)
Density 1.489 g/mL at 25 °C(lit.)
Flash Point 78 °C
Flash Point 172 °F
Refractive Index n20/D 1.490(lit.)
Refractive Index n20/D 1.490
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
RID/ADR UN 2810 6.1/PG 2
Risk Statements 36/37/38
RTECS AS4900000
Safety Statements 26-36
Storage Temperature 2-8°C
Hazard Class 6.1
UN Number 2810
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Reagent used for the synthesis of α-methylene-γ-butyrolactones from ketones and of corresponding butyrolactams from imines1,2,3,4,5; Preparation of fused piperidines from cyclic ketones6,7
Description (简体中文)
Other Notes
用于由酮合成 α-亚甲基-γ-丁内酯以及由亚胺合成相应的丁内酰胺1,2,3,4,5;由环酮制备稠合哌啶类化合物6,7

REFERENCES