trans-3-(Trimethylsilyl)allyl alcohol

• Catalog No.: 92734
• CAS Number: 59376-64-6
• M. F.: C6H14OSi
• M. W.: 130.26026
• Purity: ≥97.0% (GC)

SYNONYMS

• Title: 反式-3-(三甲基硅基)烯丙醇
• IUPAC name: (1E)-3-(trimethylsilyl)prop-1-en-1-ol
• IUPAC Traditional name: (1E)-3-(trimethylsilyl)prop-1-en-1-ol
• Synonyms: 反式-(3-羟基-2-丙烯-1-基)三甲基硅烷; 反式-3-(三甲基硅基)-2-丙烯-1-醇; trans-3-(Trimethylsilyl)-2-propen-1-ol; trans-(3-Hydroxy-2-propen-1-yl)trimethylsilane

DATABASE IDS

• PubChem SID: 24889699
• CAS Number: 59376-64-6
• Beilstein Number: 1902497
• MDL Number: MFCD00077889

PROPERTIES

• Grade: purum
• Linear Formula: (CH3)3SiCH=CHCH2OH
• Purity: ≥97.0% (GC)
• Shipped in: wet ice
• Boiling Point: 166-168 °C(lit.)
• Density: 0.848 g/mL at 25 °C(lit.)
• Flash Point: 58 °C
• Flash Point: 136.4 °F
• Refractive Index: n20/D 1.444(lit.)
• Refractive Index: n20/D 1.444
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• RID/ADR: UN 1993 3/PG 3
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• Storage Temperature: -20°C
• Hazard Class: 3
• UN Number: 1993
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Claisen rearrengement with enol ethers yields trimethylsilylated enones, interesting intermediates1

Description (简体中文)

Other Notes
烯醇醚的 Claisen 重排反应可生成让人感兴趣的中间体三甲基硅烯酮1