(+)-Noe’s reagent

• Catalog No.: 74152
• CAS Number: 87248-50-8
• M. F.: C24H38O3
• M. W.: 374.55672
• Purity: ≥98.0% (GC)

SYNONYMS

• Title: (+)-欧沃豪斯试剂
• IUPAC name: (1R,2S,4R,6S,7R)-1,10,10-trimethyl-4-{[(1R,2S,4R,6S,7R)-1,10,10-trimethyl-3-oxatricyclo[5.2.1.0^2,^6]decan-4-yl]oxy}-3-oxatricyclo[5.2.1.0^2,^6]decane
• IUPAC Traditional name: (1R,2S,4R,6S,7R)-1,10,10-trimethyl-4-{[(1R,2S,4R,6S,7R)-1,10,10-trimethyl-3-oxatricyclo[5.2.1.0^2,^6]decan-4-yl]oxy}-3-oxatricyclo[5.2.1.0^2,^6]decane
• Synonyms: (2R,3aS,4R,7aS)-Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl ether; Bis[(2R,3aS,4R,7aS)octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl] ether; (+)-MBF-OH dimer; (+)-MBF-羟基二聚物; (2R,3aS,4R,7aS)-八氢-7,8,8-三甲基-4,7-亚甲基苯并呋喃-2-基醚; 双[(2R,3aS,4R,7aS)八氢-7,8,8-三甲基-4,7-亚甲基苯并呋喃-2-基]醚

DATABASE IDS

• CAS Number: 87248-50-8
• Beilstein Number: 5756338
• MDL Number: MFCD00074783

PROPERTIES

• Empirical Formula (Hill Notation): C24H38O3
• Grade: purum
• Purity: ≥98.0% (GC)
• Melting Point: 149-151 °C
• Optical Rotation: [α]20/D +205±3°, c = 2.5% in THF
• Safety Statements: 22-24/25
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Reagent for introducing the optically active MBF group; the MBF derivatives are used for resolution and for asymmetric inductions1,2,3,4,5

Description (简体中文)

Other Notes
用于引入光学活性 MBF 基团的试剂；MBF 衍生物用于分离和不对称诱导1,2,3,4,5