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Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate_Molecular_structure_CAS_680-15-9)
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Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate

Catalog No. 36936 Name Sigma Aldrich
CAS Number 680-15-9 Website http://www.sigmaaldrich.com
M. F. C3H3F3O4S Telephone 1-800-521-8956
M. W. 192.1137296 Fax
Purity ≥95.0% (T) Email
Storage Chembase ID: 6442

SYNONYMS

Title
2,2-二氟-2-(氟磺酰基)乙酸甲酯
IUPAC name
methyl 2,2-difluoro-2-(fluorosulfonyl)acetate
IUPAC Traditional name
methyl 2,2-difluoro-2-(fluorosulfonyl)acetate

DATABASE IDS

Beilstein Number 1812896
CAS Number 680-15-9
MDL Number MFCD00144316
PubChem SID 24862961

PROPERTIES

Grade purum
Linear Formula FSO2CF2CO2CH3
Purity ≥95.0% (T)
Boiling Point 117-118 °C(lit.)
Density 1.509 g/mL at 25 °C(lit.)
Flash Point 47 °C
Flash Point 116.6 °F
Refractive Index n20/D 1.351(lit.)
Refractive Index n20/D 1.351
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Caution
may discolor to brown on storage
Other Notes
Reagent used for the trifluoromethylation of aryl, alkenyl and alkyl halides1
Description (简体中文)
Caution
储存期间可能变为棕色
Other Notes
用于芳基、烯基和烷基卤化物的三氟甲基化试剂1

REFERENCES