Dibromoborane dimethyl sulfide complex solution

• Catalog No.: 34035
• CAS Number: 55671-55-1
• M. F.: C2H7BBr2S
• M. W.: 233.76098

SYNONYMS

• Title: 二溴硼烷二甲基硫醚络合物 溶液
• IUPAC name: (methylsulfanyl)methane; dibromoborane
• IUPAC Traditional name: dibromoborane; dimethyl sulfide
• Synonyms: Dibromoborane dimethyl sulfide solution; Dibromoborane compound with dimethylsulfane solution; Dibromo(dimethyl sulfide)borane solution; Dibromo(dimethyl sulfide)(hydro)boron solution

DATABASE IDS

• MDL Number: MFCD00011601
• Beilstein Number: 4449985
• PubChem SID: 24860801
• CAS Number: 55671-55-1

PROPERTIES

• Concentration: ~1 M in methylene chloride
• Grade: technical
• Linear Formula: (CH3)2S · BHBr2
• Flash Point: 27 °C
• Flash Point: 80.6 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H261-H314-H351
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• GHS Precautionary statements: P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 2920 8/PG 2
• Risk Statements: 10-14/15-34-40
• Safety Statements: 26-36/37/39-43-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 8
• UN Number: 2920
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
Reactant for:
• Reductive elimination C-C bond forming reactions1
• Lithiation-borylation reaction with Hoppe′s lithiated carbamates2
• Preparation of boron analogues of uracil3
• Boronation reactions for formation of cyclic boronium salts4
• Hydroboration reactions5
• Ring opening of terminal epoxides6

Description (简体中文)

Application
Reactant for:
• Reductive elimination C-C bond forming reactions1
• Lithiation-borylation reaction with Hoppe′s lithiated carbamates2
• Preparation of boron analogues of uracil3
• Boronation reactions for formation of cyclic boronium salts4
• Hydroboration reactions5
• Ring opening of terminal epoxides6