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p-Tolyl [2-(trimethylsilyl)ethynyl] sulfone_Molecular_structure_CAS_34452-56-7)
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p-Tolyl [2-(trimethylsilyl)ethynyl] sulfone

Catalog No. 90135 Name Sigma Aldrich
CAS Number 34452-56-7 Website http://www.sigmaaldrich.com
M. F. C12H16O2SSi Telephone 1-800-521-8956
M. W. 252.40474 Fax
Purity ≥97.0% (CHN) Email
Storage Chembase ID: 146044

SYNONYMS

Title
对甲苯基[2-(三甲基甲硅烷基)乙炔基]砜
IUPAC name
trimethyl[2-(4-methylbenzenesulfonyl)ethynyl]silane
IUPAC Traditional name
trimethyl[2-(4-methylbenzenesulfonyl)ethynyl]silane
Synonyms
1-(对甲苯磺酰基)-2-(三甲基甲硅烷基)乙炔
2-(三甲基甲硅烷基)乙炔基对甲苯基砜
1-(p-Toluenesulfonyl)-2-(trimethylsilyl)acetylene
2-(Trimethylsilyl)ethynyl p-tolyl sulfone

DATABASE IDS

CAS Number 34452-56-7
PubChem SID 24889308
MDL Number MFCD00192508
Beilstein Number 2650368

PROPERTIES

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Grade purum
Linear Formula (CH3)3SiC≡CSO2C6H4CH3
Purity ≥97.0% (CHN)
Melting Point 80-83 °C(lit.)

DETAILS

Description (English)
Other Notes
Powerful Michael acceptor for vinylations1,2; Sterically hindered dipolarophile for cycloadditions3,4
Description (简体中文)
Other Notes
用于乙烯化反应的强效 Michael 受体1,2;用于环加成反应的空间位阻亲偶极体3,4

REFERENCES