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(1-Ethoxycyclopropoxy)trimethylsilane_Molecular_structure_CAS_27374-25-0)
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(1-Ethoxycyclopropoxy)trimethylsilane

Catalog No. 02660 Name Sigma Aldrich
CAS Number 27374-25-0 Website http://www.sigmaaldrich.com
M. F. C8H18O2Si Telephone 1-800-521-8956
M. W. 174.31282 Fax
Purity ≥98.0% (GC) Email
Storage Chembase ID: 149921

SYNONYMS

Title
1-乙氧基-1-三甲硅氧基环丙烷
IUPAC name
(1-ethoxycyclopropoxy)trimethylsilane
IUPAC Traditional name
(1-ethoxycyclopropoxy)trimethylsilane
Synonyms
环丙基乙基三甲基甲硅烷基乙缩醛
Cyclopropanone ethyl trimethylsilyl acetal

DATABASE IDS

CAS Number 27374-25-0
Beilstein Number 1924720
MDL Number MFCD00074986
PubChem SID 24845350

PROPERTIES

Grade purum
Linear Formula C2H5OC3H4OSi(CH3)3
Purity ≥98.0% (GC)
Boiling Point 50-53 °C/22 mmHg(lit.)
Density 0.867 g/mL at 25 °C(lit.)
Flash Point 26 °C
Flash Point 78.8 °F
Refractive Index n20/D 1.407(lit.)
Refractive Index n20/D 1.408
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H226-H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 3
Risk Statements 10-36/37/38
Safety Statements 26-36
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Other Notes
Building block; preparation of zinc and titanium homo-enolates suited for homo-Reformatsky and other addition reactions 1; Precursor of 1-lithio-1-ethoxycyclopropane 2
Description (简体中文)
Other Notes
结构单元;制备锌和钛的均一烯醇化物,适合于单-Reformatsky 和其他加成反应1;1-lithio-1-乙氧基环丙烷的前体2

REFERENCES