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Triethylsilane

Catalog No. 90550 Name Sigma Aldrich
CAS Number 617-86-7 Website http://www.sigmaaldrich.com
M. F. C6H16Si Telephone 1-800-521-8956
M. W. 116.27674 Fax
Purity ≥97.0% (GC) Email
Storage Chembase ID: 134471

SYNONYMS

Title
三乙基硅烷
IUPAC name
triethylsilane
IUPAC Traditional name
triethylsilane
Synonyms
Triethylhydrosilane
Triethylsilicon hydride
NSC 93579

DATABASE IDS

Beilstein Number 1098278
EC Number 210-535-3
MDL Number MFCD00009018
CAS Number 617-86-7

PROPERTIES

Grade purum
Linear Formula (C2H5)3SiH
Purity ≥97.0% (GC)
Boiling Point 107-108 °C(lit.)
Density 0.728 g/mL at 25 °C(lit.)
Flash Point -3 °C
Flash Point 26.6 °F
Refractive Index n20/D 1.412(lit.)
Refractive Index n20/D 1.412
GHS Pictograms GHS02
GHS Signal Word Danger
GHS Hazard statements H225-H412
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P273
RID/ADR UN 1993 3/PG 2
Risk Statements 11-52/53
Safety Statements 9-16-29-33-61
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 1

DETAILS

Description (English)
Other Notes
Reagent for the reduction of various functional groups (e.g. acyl halides to aldehydes, alkyl halides and secondary alcohols to hydrocarbons), review8,9,10; Silylating agent for alcohols, phenols, etc.11,12
Application
Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5Catalyst reactivation after catalyst polymerization of styrene6Studies involving the prediction of organosilicon flash points7
Description (简体中文)
Other Notes
用于还原各种官能团(如酰基卤还原为醛,烷基卤和仲醇还原为烃)的试剂,综述8,9,10;醇、苯酚等的甲硅烷基化剂。11,12
Application
Catalyst for:
• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain1
• Redox initiated cationic polymerization2,3
• Beckmann rearrangement of cyclododecanone oxime4
• Regioselective reductive coupling of enones and allenes5Catalyst reactivation after catalyst polymerization of styrene6Studies involving the prediction of organosilicon flash points7

REFERENCES