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(S)-(-)-2-Bromopropionic acid_Molecular_structure_CAS_32644-15-8)
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(S)-(-)-2-Bromopropionic acid

Catalog No. 18167 Name Sigma Aldrich
CAS Number 32644-15-8 Website http://www.sigmaaldrich.com
M. F. C3H5BrO2 Telephone 1-800-521-8956
M. W. 152.9746 Fax
Purity ≥98.5% (sum of enantiomers, GC) Email
Storage Chembase ID: 144740

SYNONYMS

Title
(S)-(-)-2-溴丙酸
IUPAC name
(2S)-2-bromopropanoic acid
IUPAC Traditional name
(2S)-2-bromopropanoic acid

DATABASE IDS

MDL Number MFCD00137325
CAS Number 32644-15-8
Beilstein Number 1720261
PubChem SID 24850951

PROPERTIES

Grade purum
Linear Formula CH3CH(Br)CO2H
Purity ≥98.5% (sum of enantiomers, GC)
Boiling Point 78 °C/4 mmHg(lit.)
Density 1.696 g/mL at 20 °C(lit.)
Flash Point 102 °C
Flash Point 215.6 °F
Melting Point -35 °C(lit.)
Optical Rotation [α]20/D -26.5±2°, neat
Refractive Index n20/D 1.475
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H302-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3261 8/PG 2
Risk Statements 22-34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 8
UN Number 3261
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Caution
may discolor to brownish on storage
Other Notes
Chiral building block; synthesis of N-substituted D-alanines with amines1,2; Preparation of chiral ethers and esters3,4
Description (简体中文)
Caution
储存时可变为褐色
Other Notes
手性结构单元;可与胺反应合成 N-取代 D-丙氨酸1,2;也可用于制备手性醚和酯3,4

REFERENCES