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1,1′-Bis(diphenylphosphino)ferrocene

Catalog No. 14816 Name Sigma Aldrich
CAS Number 12150-46-8 Website http://www.sigmaaldrich.com
M. F. C34H28FeP2 Telephone 1-800-521-8956
M. W. 554.378642 Fax
Purity ≥97.0% (C) Email
Storage Chembase ID: 125081

SYNONYMS

Title
1,1′-双(二苯基膦)二茂铁
IUPAC name
λ2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
IUPAC Traditional name
λ2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
Synonyms
1,1′-二茂铁二基-双(二苯基膦)
dppf
1,1′-Ferrocenediyl-bis(diphenylphosphine)

DATABASE IDS

PubChem SID 24848885
CAS Number 12150-46-8
MDL Number MFCD00001422

PROPERTIES

Empirical Formula (Hill Notation) C34H28FeP2
Grade purum
Purity ≥97.0% (C)
Melting Point 181-182 °C (dec.)(lit.)
Melting Point 181-183 °C (dec.)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Other Notes
Transition metal complexes are efficient catalysts for the cross-coupling of Grignard reagents with organic halides and related compounds1,2,3
Description (简体中文)
Other Notes
过渡金属络合物是格氏试剂与有机卤化物和相关化合物进行交叉偶联反应的有效催化剂1,2,3

REFERENCES