(Bromomethyl)chlorodimethylsilane

• Catalog No.: 17615
• CAS Number: 16532-02-8
• M. F.: C3H8BrClSi
• M. W.: 187.53812
• Purity: ≥96.0% (GC)

SYNONYMS

• Title: (溴甲基)二甲基氯硅烷
• IUPAC name: (bromomethyl)(chloro)dimethylsilane
• IUPAC Traditional name: (bromomethyl)(chloro)dimethylsilane
• Synonyms: (Bromomethyl)dimethylchlorosilane; BMDMCS

DATABASE IDS

• CAS Number: 16532-02-8
• EC Number: 240-601-7
• Beilstein Number: 1071201
• MDL Number: MFCD00000503

PROPERTIES

• RID/ADR: UN 2986 8/PG 2
• Risk Statements: 10-34
• Safety Statements: 26-36/37/39-45
• Hazard Class: 8
• UN Number: 2986
• Packing Group: 2
• German water hazard class: 3
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• Grade: purum
• Linear Formula: BrCH2Si(CH3)2Cl
• Purity: ≥96.0% (GC)
• Boiling Point: 130 °C/740 mmHg(lit.)
• Density: 1.375 g/mL at 25 °C(lit.)
• Flash Point: 41 °C
• Flash Point: 105.8 °F
• Refractive Index: n20/D 1.465(lit.)
• Refractive Index: n20/D 1.466
• Vapor Density: >1 (vs air)

DETAILS

Description (English)

Other Notes
Derivatizing agent for electron capture gas chromatography 1,2; Allylic bromomethylsilyl ethers allow the stereoselective introduction of a cis hydroxymethyl or methyl group via radical cyclization 3

Description (简体中文)

Other Notes
电子俘获气相色谱法的衍生化试剂1,2；烯丙基溴甲基硅基醚允许通过自由基环化反应，立体选择引入顺式羟甲基或甲基3