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(S,S)-2,2′-Methylenebis(4-tert-butyl-2-oxazoline)_Molecular_structure_CAS_132098-54-5)
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(S,S)-2,2′-Methylenebis(4-tert-butyl-2-oxazoline)

Catalog No. 66680 Name Sigma Aldrich
CAS Number 132098-54-5 Website http://www.sigmaaldrich.com
M. F. C15H26N2O2 Telephone 1-800-521-8956
M. W. 266.37914 Fax
Purity ≥95.0% (sum of enantiomers, GC) Email
Storage Chembase ID: 146289

SYNONYMS

Title
(S,S)-2,2′-亚甲基双(4-叔丁基-2-噁唑啉)
IUPAC name
(4S)-4-tert-butyl-2-{[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]methyl}-4,5-dihydro-1,3-oxazole
IUPAC Traditional name
(4S)-4-tert-butyl-2-{[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]methyl}-4,5-dihydro-1,3-oxazole

DATABASE IDS

Beilstein Number 4190673
MDL Number MFCD00192290
CAS Number 132098-54-5

PROPERTIES

Empirical Formula (Hill Notation) C15H26N2O2
Grade purum
Purity ≥95.0% (sum of enantiomers, GC)
Melting Point 50-53 °C(lit.)
Melting Point 50-53 °C
Optical Rotation [α]20/D -114±3°, c = 0.5% in chloroform stab. with amylenes
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Risk Statements 36/37/38
Safety Statements 26-36
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Other Notes
Catalyst for the enantioselective cyclopropanation of olefins with diazoesters1,2
Description (简体中文)
Other Notes
催化剂,用于重氮酯作用下烯烃的对映选择性环丙烷化1,2

REFERENCES