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Triethyl phosphite

Catalog No. 90540 Name Sigma Aldrich
CAS Number 122-52-1 Website http://www.sigmaaldrich.com
M. F. C6H15O3P Telephone 1-800-521-8956
M. W. 166.155261 Fax
Purity ≥95.0% (GC) Email
Storage Chembase ID: 104745

SYNONYMS

Title
亚磷酸三乙酯
IUPAC name
triethyl phosphite
IUPAC Traditional name
triethyl phosphite
Synonyms
P(OEt)3
P(EtO)3

DATABASE IDS

Beilstein Number 956578
MDL Number MFCD00009084
PubChem SID 24889381
EC Number 204-552-5
CAS Number 122-52-1

PROPERTIES

Grade purum
Linear Formula (C2H5O)3P
Purity ≥95.0% (GC)
Boiling Point 156 °C(lit.)
Density 0.969 g/mL at 25 °C(lit.)
Flash Point 54 °C
Flash Point 129.2 °F
Refractive Index n20/D 1.413(lit.)
Refractive Index n20/D 1.413
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H226-H302-H315-H319-H332-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
RID/ADR UN 2323 3/PG 3
Risk Statements 10-22-36/37/38
RTECS TH1130000
Safety Statements 16-26-36
Hazard Class 3
UN Number 2323
Packing Group 3
German water hazard class 1

DETAILS

Description (English)
Other Notes
This phosphite is less reactive than triphenylphosphine but can lead to a more favorable diastereomer ratio in products1,2
Description (简体中文)
Other Notes
该亚磷酸酯的活性低于三苯基膦,但所得产物中的非对映体比例更好1,2

REFERENCES