(+)-Methyl (R)-3-bromo-2-methylpropionate

• Catalog No.: 17616
• CAS Number: 110556-33-7
• M. F.: C5H9BrO2
• M. W.: 181.02776
• Purity: ≥95.0% (sum of enantiomers, GC)

SYNONYMS

• Title: (+)-(R)-3-溴-2-甲基丙酸甲酯
• IUPAC name: methyl (2R)-3-bromo-2-methylpropanoate
• IUPAC Traditional name: methyl (2R)-3-bromo-2-methylpropanoate
• Synonyms: (+)-(R)-β-溴异丁酸甲酯; (+)-Methyl (R)-β-bromoisobutyrate

DATABASE IDS

• MDL Number: MFCD00010639
• CAS Number: 110556-33-7
• Beilstein Number: 1720833

PROPERTIES

• Empirical Formula (Hill Notation): C5H9BrO2
• Grade: purum
• Purity: ≥95.0% (sum of enantiomers, GC)
• Boiling Point: 85 °C/37 mmHg(lit.)
• Density: 1.417 g/mL at 20 °C(lit.)
• Flash Point: 73 °C
• Flash Point: 163.4 °F
• Optical Rotation: [α]20/D +16±1°, neat
• Refractive Index: n20/D 1.455
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Preparation of chiral zinc enolate via a cyclopropane1,2

Description (简体中文)

Other Notes
通过环丙烷制备锌的手性烯醇化物1,2